Redox cycling of Ni-YSZ anodes for solid oxide fuel cells: influence of tortuosity, constriction and percolation factors on the effective transport properties

Holzer, Lorenz; Iwanschitz, Boris; Hocker, Thomas; Keller, Lukas; Pecho, Omar; Sartoris, Guido; Gasser, Philippe; Muench, Beat

doi:10.1016/j.jpowsour.2013.05.047

Publication type:	Article in scientific journal
Type of review:	Peer review (publication)
Title:	Redox cycling of Ni-YSZ anodes for solid oxide fuel cells: influence of tortuosity, constriction and percolation factors on the effective transport properties
Authors:	Holzer, Lorenz Iwanschitz, Boris Hocker, Thomas Keller, Lukas Pecho, Omar Sartoris, Guido Gasser, Philippe Muench, Beat
DOI:	10.1016/j.jpowsour.2013.05.047
Published in:	Journal of Power Sources
Volume(Issue):	242
Page(s):	179
Pages to:	194
Issue Date:	2013
Publisher / Ed. Institution:	Elsevier
ISSN:	0378-7753 1873-2755
Language:	English
Subjects:	Map; SOFC
Subject (DDC):	621.3: Electrical, communications, control engineering
Abstract:	A methodology based on FIB-tomography and image analysis (IA) is proposed which allows quantification of all relevant morphological features that are necessary to predict effective transport properties in porous SOFC electrodes. These morphological Features are constrictivity, tortuosity, percolation factor and phase volume fraction. An M-factor can then be calculated which represents the ratio of effective over intrinsic conductivities. The methodology is used to describe effects of microstructure degradation in Ni-YSZ anodes which are caused by redox cycling at 950°C. The so calculated M-factors predict that because of redox cycling the effective electronic conductivity of nickel decreases from 3 to 1.2% which is mainly due to changes of percolation and constriction factors. Based on these results the effective electrical conductivity of nickel is predicted to be 685 S/cm before redox and 243 S/cm after 8 redox cycles. The predictions fit well with the experimental measurements that reveal 600 S/cm before and 200 S/cm after redox cycling at 950°C. For YSZ the M-factors obtained with 3D-analysis predict that the degradation causes a drop of the effective ionic conductivity from 7 to 0.6%, which is due to a change of the bottleneck dimensions. This finding contradicts the frequent interpretation of YSZ as a ‘rigid backbone’ that is not affected by microstructure degradation. Finally, the effective bulk gas diffusivity increases from 2 to 11% due to an increase of porosity associated with swelling of the anode.
URI:	https://digitalcollection.zhaw.ch/handle/11475/1619
Fulltext version:	Published version
License (according to publishing contract):	Licence according to publishing contract
Departement:	School of Engineering
Organisational Unit:	Institute of Computational Physics (ICP)
Appears in collections:	Publikationen School of Engineering

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Holzer, L., Iwanschitz, B., Hocker, T., Keller, L., Pecho, O., Sartoris, G., Gasser, P., & Muench, B. (2013). Redox cycling of Ni-YSZ anodes for solid oxide fuel cells: influence of tortuosity, constriction and percolation factors on the effective transport properties. Journal of Power Sources, 242, 179–194. https://doi.org/10.1016/j.jpowsour.2013.05.047

Holzer, L. et al. (2013) ‘Redox cycling of Ni-YSZ anodes for solid oxide fuel cells: influence of tortuosity, constriction and percolation factors on the effective transport properties’, Journal of Power Sources, 242, pp. 179–194. Available at: https://doi.org/10.1016/j.jpowsour.2013.05.047.

L. Holzer et al., “Redox cycling of Ni-YSZ anodes for solid oxide fuel cells: influence of tortuosity, constriction and percolation factors on the effective transport properties,” Journal of Power Sources, vol. 242, pp. 179–194, 2013, doi: 10.1016/j.jpowsour.2013.05.047.

HOLZER, Lorenz, Boris IWANSCHITZ, Thomas HOCKER, Lukas KELLER, Omar PECHO, Guido SARTORIS, Philippe GASSER und Beat MUENCH, 2013. Redox cycling of Ni-YSZ anodes for solid oxide fuel cells: influence of tortuosity, constriction and percolation factors on the effective transport properties. Journal of Power Sources. 2013. Bd. 242, S. 179–194. DOI 10.1016/j.jpowsour.2013.05.047

Holzer, Lorenz, Boris Iwanschitz, Thomas Hocker, Lukas Keller, Omar Pecho, Guido Sartoris, Philippe Gasser, and Beat Muench. 2013. “Redox Cycling of Ni-YSZ Anodes for Solid Oxide Fuel Cells: Influence of Tortuosity, Constriction and Percolation Factors on the Effective Transport Properties.” Journal of Power Sources 242: 179–94. https://doi.org/10.1016/j.jpowsour.2013.05.047.

Holzer, Lorenz, et al. “Redox Cycling of Ni-YSZ Anodes for Solid Oxide Fuel Cells: Influence of Tortuosity, Constriction and Percolation Factors on the Effective Transport Properties.” Journal of Power Sources, vol. 242, 2013, pp. 179–94, https://doi.org/10.1016/j.jpowsour.2013.05.047.