Publication type: | Conference paper |
Type of review: | Peer review (abstract) |
Title: | LST27 anodes for SOFCs : redox stable and sulfur tolerant material |
Authors: | Madi, Hossein Burnat, Dariusz Artur Mai, Andreas Heel, Andre Van Herle, Jan |
Proceedings: | Proceedings of 13th European SOFC & SOE Forum 2018 |
Conference details: | 13th European SOFC & SOE Forum 2018, Lucerne, 3-6 July 2018 |
Issue Date: | 2018 |
Language: | English |
Subjects: | Anodes; Perovskite; Smart Material; SOFC |
Subject (DDC): | 621.3: Electrical, communications, control engineering |
Abstract: | Fuel flexibility is a major advantage of SOFCs, which allows the use of hydrocarbon fuels. These fuels may contain trace amount of H2S, which causes a drop in performance with the conventional Ni-based anode catalysts. Thereby, it is highly desirable to develop novel sulfur tolerant anode materials. A new ceramic based on B-site substitution of titanium with nickel in lanthanum-doped strontium titanates catalyst, was investigated (La0.2Sr0.7Ti0.95Ni0.05O3-δ or LST27). The material shows promising tolerance towards sulfur poisoning and reductionoxidation (“redox”) cycling. Three samples - LST27, LST27 impregnated with 5 wt.% Ni, and LST 27 impregnated with 5 wt.% Ni and 10 wt.% CeO2 - were evaluated for their behavior with respect to redox cycle tolerance and poisoning with H2S. Results showed that the anode withstands redox cycles; subsequently, a redox cycle is exploited to recover anode performance after expos to H2S. In other words, this anode can be regenerated from sulfur poisoning and thereby extend SOFC lifetime. |
Further description: | B0929 |
URI: | https://digitalcollection.zhaw.ch/handle/11475/8936 |
Fulltext version: | Published version |
License (according to publishing contract): | Not specified |
Departement: | School of Engineering |
Organisational Unit: | Institute of Materials and Process Engineering (IMPE) |
Published as part of the ZHAW project: | SERAN - Self-Regenerating Anodes: Durability Improvement of SOFC Technology by Novel Smart Materials with Sulphur Tolerance |
Appears in collections: | Publikationen School of Engineering |
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Madi, H., Burnat, D. A., Mai, A., Heel, A., & Van Herle, J. (2018). LST27 anodes for SOFCs : redox stable and sulfur tolerant material. Proceedings of 13th European SOFC & SOE Forum 2018.
Madi, H. et al. (2018) ‘LST27 anodes for SOFCs : redox stable and sulfur tolerant material’, in Proceedings of 13th European SOFC & SOE Forum 2018.
H. Madi, D. A. Burnat, A. Mai, A. Heel, and J. Van Herle, “LST27 anodes for SOFCs : redox stable and sulfur tolerant material,” in Proceedings of 13th European SOFC & SOE Forum 2018, 2018.
MADI, Hossein, Dariusz Artur BURNAT, Andreas MAI, Andre HEEL und Jan VAN HERLE, 2018. LST27 anodes for SOFCs : redox stable and sulfur tolerant material. In: Proceedings of 13th European SOFC & SOE Forum 2018. Conference paper. 2018
Madi, Hossein, Dariusz Artur Burnat, Andreas Mai, Andre Heel, and Jan Van Herle. 2018. “LST27 Anodes for SOFCs : Redox Stable and Sulfur Tolerant Material.” Conference paper. In Proceedings of 13th European SOFC & SOE Forum 2018.
Madi, Hossein, et al. “LST27 Anodes for SOFCs : Redox Stable and Sulfur Tolerant Material.” Proceedings of 13th European SOFC & SOE Forum 2018, 2018.
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