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dc.contributor.authorHonciuc, Andrei-
dc.contributor.authorJaiswal, Archana-
dc.contributor.authorGong, Aijun-
dc.contributor.authorAshworth, Kimba-
dc.contributor.authorSpangler, Charles W.-
dc.contributor.authorPeterson, Ian R.-
dc.contributor.authorDalton, Larry R.-
dc.contributor.authorMetzger, Robert M.-
dc.date.accessioned2018-12-11T15:45:35Z-
dc.date.available2018-12-11T15:45:35Z-
dc.date.issued2005-
dc.identifier.issn1520-6106de_CH
dc.identifier.issn1520-5207de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/13743-
dc.description.abstractLangmuir-Schaefer (LS) monolayer films of fullerene-bis-[4-diphenylamino-4' '-(N-ethyl-N-2' ''-ethyl)amino-1,4-diphenyl-1,3-butadiene] malonate, 1, sandwiched between two Au electrodes, exhibit pronounced current asymmetries (rectification) between positive and negative bias at room temperature, with no decay of the rectification after several cycles. The device shows symmetrical through-space tunneling for a bias up to +/-3 V, and asymmetrical, unimolecular, "U" type rectifier behavior in the voltage range from +/-3.0 to +/-5.4 V, with rectification ratios up to 16.5. The rectification is ascribed to the asymmetric placement of the relevant molecular orbitals, with respect to the metallic electrodes.de_CH
dc.language.isoende_CH
dc.publisherAmerican Chemical Societyde_CH
dc.relation.ispartofThe Journal of Physical Chemistry Bde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectAirde_CH
dc.subjectDiphenylaminede_CH
dc.subjectElectrochemistryde_CH
dc.subjectElectrodesde_CH
dc.subjectFullerenesde_CH
dc.subjectGoldde_CH
dc.subjectChemical modelsde_CH
dc.subjectMolecular structurede_CH
dc.subjectSensitivity and specificityde_CH
dc.subjectUltraviolet spectrophotometryde_CH
dc.subjectSurface propertiesde_CH
dc.subjectWaterde_CH
dc.subjectArtificial membranesde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleCurrent rectification in a Langmuir−Schaefer monolayer of fullerene-bis-[4-diphenylamino-4‘ ‘-(N-ethyl-N-2‘ ‘‘-ethyl)amino-1,4-diphenyl-1,3-butadiene] malonate between Au electrodesde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
dc.identifier.doi10.1021/jp0454624de_CH
dc.identifier.pmid16866452de_CH
zhaw.funding.euNode_CH
zhaw.issue2de_CH
zhaw.originated.zhawNode_CH
zhaw.pages.end871de_CH
zhaw.pages.start857de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume109de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
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Honciuc, A., Jaiswal, A., Gong, A., Ashworth, K., Spangler, C. W., Peterson, I. R., Dalton, L. R., & Metzger, R. M. (2005). Current rectification in a Langmuir−Schaefer monolayer of fullerene-bis-[4-diphenylamino-4‘ ‘-(N-ethyl-N-2‘ ‘’-ethyl)amino-1,4-diphenyl-1,3-butadiene] malonate between Au electrodes. The Journal of Physical Chemistry B, 109(2), 857–871. https://doi.org/10.1021/jp0454624
Honciuc, A. et al. (2005) ‘Current rectification in a Langmuir−Schaefer monolayer of fullerene-bis-[4-diphenylamino-4‘ ‘-(N-ethyl-N-2‘ ‘‘-ethyl)amino-1,4-diphenyl-1,3-butadiene] malonate between Au electrodes’, The Journal of Physical Chemistry B, 109(2), pp. 857–871. Available at: https://doi.org/10.1021/jp0454624.
A. Honciuc et al., “Current rectification in a Langmuir−Schaefer monolayer of fullerene-bis-[4-diphenylamino-4‘ ‘-(N-ethyl-N-2‘ ‘’-ethyl)amino-1,4-diphenyl-1,3-butadiene] malonate between Au electrodes,” The Journal of Physical Chemistry B, vol. 109, no. 2, pp. 857–871, 2005, doi: 10.1021/jp0454624.
HONCIUC, Andrei, Archana JAISWAL, Aijun GONG, Kimba ASHWORTH, Charles W. SPANGLER, Ian R. PETERSON, Larry R. DALTON und Robert M. METZGER, 2005. Current rectification in a Langmuir−Schaefer monolayer of fullerene-bis-[4-diphenylamino-4‘ ‘-(N-ethyl-N-2‘ ‘‘-ethyl)amino-1,4-diphenyl-1,3-butadiene] malonate between Au electrodes. The Journal of Physical Chemistry B. 2005. Bd. 109, Nr. 2, S. 857–871. DOI 10.1021/jp0454624
Honciuc, Andrei, Archana Jaiswal, Aijun Gong, Kimba Ashworth, Charles W. Spangler, Ian R. Peterson, Larry R. Dalton, and Robert M. Metzger. 2005. “Current Rectification in a Langmuir−Schaefer Monolayer of Fullerene-Bis-[4-Diphenylamino-4‘ ‘-(N-Ethyl-N-2‘ ‘’-Ethyl)amino-1,4-Diphenyl-1,3-Butadiene] Malonate between Au Electrodes.” The Journal of Physical Chemistry B 109 (2): 857–71. https://doi.org/10.1021/jp0454624.
Honciuc, Andrei, et al. “Current Rectification in a Langmuir−Schaefer Monolayer of Fullerene-Bis-[4-Diphenylamino-4‘ ‘-(N-Ethyl-N-2‘ ‘’-Ethyl)amino-1,4-Diphenyl-1,3-Butadiene] Malonate between Au Electrodes.” The Journal of Physical Chemistry B, vol. 109, no. 2, 2005, pp. 857–71, https://doi.org/10.1021/jp0454624.


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