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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shumate, Walter J. | - |
dc.contributor.author | Mattern, Daniell L. | - |
dc.contributor.author | Jaiswal, Archana | - |
dc.contributor.author | Dixon, David A. | - |
dc.contributor.author | White, Tina Renea | - |
dc.contributor.author | Burgess, James | - |
dc.contributor.author | Honciuc, Andrei | - |
dc.contributor.author | Metzger, Robert M. | - |
dc.date.accessioned | 2018-12-11T15:46:07Z | - |
dc.date.available | 2018-12-11T15:46:07Z | - |
dc.date.issued | 2006 | - |
dc.identifier.issn | 1520-6106 | de_CH |
dc.identifier.issn | 1520-5207 | de_CH |
dc.identifier.uri | https://digitalcollection.zhaw.ch/handle/11475/13744 | - |
dc.description.abstract | We report spectroscopic characterization and unimolecular rectification (asymmetric electrical conduction) measurements of three donor-sigma-acceptor (D-sigma-A) compounds N-(10-nonadecyl)-N-(1-pyrenylmethyl)perylene-3,4,9,10-bis(dicarboximide) (1), N-(10-nonadecyl)-N-(4-[1-pyrenyl]butyl)perylene-3,4,9,10-bis(dicarboximide) (2), and N-(10-nonadecyl)-N-(2-ferrocenylethyl)perylene-3,4,9,10-bis(dicarboximide) (3). These molecules were arranged as one-molecule thick Langmuir-Blodgett monolayers between Au electrodes. In such an "Au | D-sigma-A | Au" sandwich, molecule 1 is a unimolecular rectifier, with rather small rectification ratios (between 2 and 3 at +/-1 V) that decrease upon cycling. Molecule 2 does not rectify. Molecule 3 rectifies, with a rectification ratio of between 14 and 28 at +/-1 V; the through-film rectification and currents persist, even with scans of +/-2 V, for up to 40 cycles of measurement. Qualitative arguments, based on a two-level rectification mechanism, are consistent with the current asymmetries observed in the monolayers of 1 and 3. | de_CH |
dc.language.iso | en | de_CH |
dc.publisher | American Chemical Society | de_CH |
dc.relation.ispartof | The Journal of Physical Chemistry B | de_CH |
dc.rights | Licence according to publishing contract | de_CH |
dc.subject.ddc | 540: Chemie | de_CH |
dc.title | Spectroscopy and rectification of three donor−sigma−acceptor compounds, consisting of a one-electron donor (pyrene or ferrocene), a one-electron acceptor (perylenebisimide), and a C19 swallowtail | de_CH |
dc.type | Beitrag in wissenschaftlicher Zeitschrift | de_CH |
dcterms.type | Text | de_CH |
zhaw.departement | Life Sciences und Facility Management | de_CH |
dc.identifier.doi | 10.1021/jp0575512 | de_CH |
dc.identifier.pmid | 16771377 | de_CH |
zhaw.funding.eu | No | de_CH |
zhaw.issue | 23 | de_CH |
zhaw.originated.zhaw | No | de_CH |
zhaw.pages.end | 11159 | de_CH |
zhaw.pages.start | 11146 | de_CH |
zhaw.publication.status | publishedVersion | de_CH |
zhaw.volume | 110 | de_CH |
zhaw.publication.review | Peer review (Publikation) | de_CH |
Appears in collections: | Publikationen Life Sciences und Facility Management |
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Shumate, W. J., Mattern, D. L., Jaiswal, A., Dixon, D. A., White, T. R., Burgess, J., Honciuc, A., & Metzger, R. M. (2006). Spectroscopy and rectification of three donor−sigma−acceptor compounds, consisting of a one-electron donor (pyrene or ferrocene), a one-electron acceptor (perylenebisimide), and a C19 swallowtail. The Journal of Physical Chemistry B, 110(23), 11146–11159. https://doi.org/10.1021/jp0575512
Shumate, W.J. et al. (2006) ‘Spectroscopy and rectification of three donor−sigma−acceptor compounds, consisting of a one-electron donor (pyrene or ferrocene), a one-electron acceptor (perylenebisimide), and a C19 swallowtail’, The Journal of Physical Chemistry B, 110(23), pp. 11146–11159. Available at: https://doi.org/10.1021/jp0575512.
W. J. Shumate et al., “Spectroscopy and rectification of three donor−sigma−acceptor compounds, consisting of a one-electron donor (pyrene or ferrocene), a one-electron acceptor (perylenebisimide), and a C19 swallowtail,” The Journal of Physical Chemistry B, vol. 110, no. 23, pp. 11146–11159, 2006, doi: 10.1021/jp0575512.
SHUMATE, Walter J., Daniell L. MATTERN, Archana JAISWAL, David A. DIXON, Tina Renea WHITE, James BURGESS, Andrei HONCIUC und Robert M. METZGER, 2006. Spectroscopy and rectification of three donor−sigma−acceptor compounds, consisting of a one-electron donor (pyrene or ferrocene), a one-electron acceptor (perylenebisimide), and a C19 swallowtail. The Journal of Physical Chemistry B. 2006. Bd. 110, Nr. 23, S. 11146–11159. DOI 10.1021/jp0575512
Shumate, Walter J., Daniell L. Mattern, Archana Jaiswal, David A. Dixon, Tina Renea White, James Burgess, Andrei Honciuc, and Robert M. Metzger. 2006. “Spectroscopy and Rectification of Three Donor−Sigma−Acceptor Compounds, Consisting of a One-Electron Donor (Pyrene or Ferrocene), a One-Electron Acceptor (Perylenebisimide), and a C19 Swallowtail.” The Journal of Physical Chemistry B 110 (23): 11146–59. https://doi.org/10.1021/jp0575512.
Shumate, Walter J., et al. “Spectroscopy and Rectification of Three Donor−Sigma−Acceptor Compounds, Consisting of a One-Electron Donor (Pyrene or Ferrocene), a One-Electron Acceptor (Perylenebisimide), and a C19 Swallowtail.” The Journal of Physical Chemistry B, vol. 110, no. 23, 2006, pp. 11146–59, https://doi.org/10.1021/jp0575512.
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