Olefin metathesis of a ruthenium carbene complex by electrospray ionization in the gas phase

Hinderling, Christian; Adlhart, Christian; Chen, Peter

doi:10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M

Publication type:	Article in scientific journal
Type of review:	Peer review (publication)
Title:	Olefin metathesis of a ruthenium carbene complex by electrospray ionization in the gas phase
Authors:	Hinderling, Christian Adlhart, Christian Chen, Peter
DOI:	10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M
Published in:	Angewandte Chemie: International Edition
Volume(Issue):	37
Issue:	19
Page(s):	2685
Pages to:	2689
Issue Date:	16-Oct-1998
Publisher / Ed. Institution:	Wiley
Publisher / Ed. Institution:	Hoboken
ISSN:	1433-7851 0570-0833
Language:	English
Subjects:	Gas-phase chemistry; Mass spectrometry; Metathesis; Carbene complexes
Subject (DDC):	660: Chemical engineering
Abstract:	Surprisingly similar reactions in the gas phase and in solution [Eq. (a)]: The ion 1 obtained by electrospray ionization behaves in the gas phase analogously to the corresponding complex [RuCl2(=CHPh)(PCy3)2] in solution. Measured relative rates for ring-opening metathesis are interpreted under the assumption of an intramolecular π complex, which leads to an estimation of the equilibrium constant for π complexation.
URI:	https://digitalcollection.zhaw.ch/handle/11475/2086
Fulltext version:	Published version
License (according to publishing contract):	Licence according to publishing contract
Departement:	Life Sciences and Facility Management
Organisational Unit:	Institute of Chemistry and Biotechnology (ICBT)
Appears in collections:	Publikationen Life Sciences und Facility Management

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Hinderling, C., Adlhart, C., & Chen, P. (1998). Olefin metathesis of a ruthenium carbene complex by electrospray ionization in the gas phase. Angewandte Chemie: International Edition, 37(19), 2685–2689. https://doi.org/10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M

Hinderling, C., Adlhart, C. and Chen, P. (1998) ‘Olefin metathesis of a ruthenium carbene complex by electrospray ionization in the gas phase’, Angewandte Chemie: International Edition, 37(19), pp. 2685–2689. Available at: https://doi.org/10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M.

C. Hinderling, C. Adlhart, and P. Chen, “Olefin metathesis of a ruthenium carbene complex by electrospray ionization in the gas phase,” Angewandte Chemie: International Edition, vol. 37, no. 19, pp. 2685–2689, Oct. 1998, doi: 10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M.

HINDERLING, Christian, Christian ADLHART und Peter CHEN, 1998. Olefin metathesis of a ruthenium carbene complex by electrospray ionization in the gas phase. Angewandte Chemie: International Edition. 16 Oktober 1998. Bd. 37, Nr. 19, S. 2685–2689. DOI 10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M

Hinderling, Christian, Christian Adlhart, and Peter Chen. 1998. “Olefin Metathesis of a Ruthenium Carbene Complex by Electrospray Ionization in the Gas Phase.” Angewandte Chemie: International Edition 37 (19): 2685–89. https://doi.org/10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M.

Hinderling, Christian, et al. “Olefin Metathesis of a Ruthenium Carbene Complex by Electrospray Ionization in the Gas Phase.” Angewandte Chemie: International Edition, vol. 37, no. 19, Oct. 1998, pp. 2685–89, https://doi.org/10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M.