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dc.contributor.authorAdlhart, Christian-
dc.contributor.authorVolland, Martin A. O.-
dc.contributor.authorHofmann, Peter-
dc.contributor.authorChen, Peter-
dc.date.accessioned2018-01-17T12:15:56Z-
dc.date.available2018-01-17T12:15:56Z-
dc.date.issued2000-12-20-
dc.identifier.issn0018-019Xde_CH
dc.identifier.issn1522-2675de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/2090-
dc.description.abstractA gas-phase comparison of intrinsic olefin metathesis rates for (carbene)ruthenium complexes by means of electrospray-ionization tandem mass spectrometry reveals a reversal of the reactivity trends observed in solution. The solution-phase ordering of reactivity is accordingly attributed to a more favorable pre-equilibrium, producing the metathesis-active species in the case of the Hofmann- and Werner-type complexes relative to those of the Grubbs type.de_CH
dc.language.isoende_CH
dc.publisherWileyde_CH
dc.relation.ispartofHelvetica Chimica Actade_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectMetathesis kineticsde_CH
dc.subjectReaction mechanismde_CH
dc.subjectElectrospray ionization mass spectrometryde_CH
dc.subjectEquilibriumde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleComparing Grubbs-, Werner-, and Hofmann-type (carbene)ruthenium complexes : the key role of pre-equilibria for olefin metathesisde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
zhaw.organisationalunitInstitut für Chemie und Biotechnologie (ICBT)de_CH
zhaw.publisher.placeHobokende_CH
dc.identifier.doi10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7de_CH
zhaw.funding.euNode_CH
zhaw.issue12de_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end3311de_CH
zhaw.pages.start3306de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume83de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
Appears in collections:Publikationen Life Sciences und Facility Management

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Adlhart, C., Volland, M. A. O., Hofmann, P., & Chen, P. (2000). Comparing Grubbs-, Werner-, and Hofmann-type (carbene)ruthenium complexes : the key role of pre-equilibria for olefin metathesis. Helvetica Chimica Acta, 83(12), 3306–3311. https://doi.org/10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7
Adlhart, C. et al. (2000) ‘Comparing Grubbs-, Werner-, and Hofmann-type (carbene)ruthenium complexes : the key role of pre-equilibria for olefin metathesis’, Helvetica Chimica Acta, 83(12), pp. 3306–3311. Available at: https://doi.org/10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7.
C. Adlhart, M. A. O. Volland, P. Hofmann, and P. Chen, “Comparing Grubbs-, Werner-, and Hofmann-type (carbene)ruthenium complexes : the key role of pre-equilibria for olefin metathesis,” Helvetica Chimica Acta, vol. 83, no. 12, pp. 3306–3311, Dec. 2000, doi: 10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7.
ADLHART, Christian, Martin A. O. VOLLAND, Peter HOFMANN und Peter CHEN, 2000. Comparing Grubbs-, Werner-, and Hofmann-type (carbene)ruthenium complexes : the key role of pre-equilibria for olefin metathesis. Helvetica Chimica Acta. 20 Dezember 2000. Bd. 83, Nr. 12, S. 3306–3311. DOI 10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7
Adlhart, Christian, Martin A. O. Volland, Peter Hofmann, and Peter Chen. 2000. “Comparing Grubbs-, Werner-, and Hofmann-Type (Carbene)ruthenium Complexes : The Key Role of Pre-Equilibria for Olefin Metathesis.” Helvetica Chimica Acta 83 (12): 3306–11. https://doi.org/10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7.
Adlhart, Christian, et al. “Comparing Grubbs-, Werner-, and Hofmann-Type (Carbene)ruthenium Complexes : The Key Role of Pre-Equilibria for Olefin Metathesis.” Helvetica Chimica Acta, vol. 83, no. 12, Dec. 2000, pp. 3306–11, https://doi.org/10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7.


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