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dc.contributor.authorSalmio, Hanna-
dc.contributor.authorBrühwiler, Dominik-
dc.date.accessioned2018-01-31T10:28:43Z-
dc.date.available2018-01-31T10:28:43Z-
dc.date.issued2007-
dc.identifier.issn1932-7447de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/2348-
dc.description.abstractThe reaction of mesoporous silica MCM-41 with various aminopropylsilanes was investigated. The distribution of grafted amino groups after submonolayer deposition from anhydrous toluene was probed by fluorescein labeling in conjunction with photoluminescence spectroscopy and pore size analysis. Monoalkoxysilanes generally distributed more uniformly than monopodal and dipodal trialkoxysilanes. The outcome of the grafting reaction additionally depended on the nature of the amino group. Secondary amines grafted more efficiently than their primary analogues. Moreover, it was found that the polarity of the solvent strongly affects the distribution of the amino groups in the case of strongly interacting aminopropylsilanes.de_CH
dc.language.isoende_CH
dc.publisherAmerican Chemical Societyde_CH
dc.relation.ispartofJournal of Physical Chemistry Cde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectSilicade_CH
dc.subjectMesoporesde_CH
dc.subjectAminede_CH
dc.subjectFunctionalizationde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleDistribution of amino groups on a mesoporous silica surface after submonolayer deposition of aminopropylsilanes from an anhydrous liquid phasede_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
dc.identifier.doi10.1021/jp0651440de_CH
zhaw.funding.euNode_CH
zhaw.issue2de_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end929de_CH
zhaw.pages.start923de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume111de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
Appears in collections:Publikationen Life Sciences und Facility Management

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Salmio, H., & Brühwiler, D. (2007). Distribution of amino groups on a mesoporous silica surface after submonolayer deposition of aminopropylsilanes from an anhydrous liquid phase. Journal of Physical Chemistry C, 111(2), 923–929. https://doi.org/10.1021/jp0651440
Salmio, H. and Brühwiler, D. (2007) ‘Distribution of amino groups on a mesoporous silica surface after submonolayer deposition of aminopropylsilanes from an anhydrous liquid phase’, Journal of Physical Chemistry C, 111(2), pp. 923–929. Available at: https://doi.org/10.1021/jp0651440.
H. Salmio and D. Brühwiler, “Distribution of amino groups on a mesoporous silica surface after submonolayer deposition of aminopropylsilanes from an anhydrous liquid phase,” Journal of Physical Chemistry C, vol. 111, no. 2, pp. 923–929, 2007, doi: 10.1021/jp0651440.
SALMIO, Hanna und Dominik BRÜHWILER, 2007. Distribution of amino groups on a mesoporous silica surface after submonolayer deposition of aminopropylsilanes from an anhydrous liquid phase. Journal of Physical Chemistry C. 2007. Bd. 111, Nr. 2, S. 923–929. DOI 10.1021/jp0651440
Salmio, Hanna, and Dominik Brühwiler. 2007. “Distribution of Amino Groups on a Mesoporous Silica Surface after Submonolayer Deposition of Aminopropylsilanes from an Anhydrous Liquid Phase.” Journal of Physical Chemistry C 111 (2): 923–29. https://doi.org/10.1021/jp0651440.
Salmio, Hanna, and Dominik Brühwiler. “Distribution of Amino Groups on a Mesoporous Silica Surface after Submonolayer Deposition of Aminopropylsilanes from an Anhydrous Liquid Phase.” Journal of Physical Chemistry C, vol. 111, no. 2, 2007, pp. 923–29, https://doi.org/10.1021/jp0651440.


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