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dc.contributor.authorFois, Ettore-
dc.contributor.authorTabacchi, Gloria-
dc.contributor.authorDevaux, André-
dc.contributor.authorBelser, Peter-
dc.contributor.authorBrühwiler, Dominik-
dc.contributor.authorCalzaferri, Gion-
dc.date.accessioned2018-02-05T10:52:59Z-
dc.date.available2018-02-05T10:52:59Z-
dc.date.issued2013-
dc.identifier.issn0743-7463de_CH
dc.identifier.issn1520-5827de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/2613-
dc.description.abstractA combined experimental and modeling study of methylacridine (MeAcr+) dye-zeolite L composites unravels the microscopic origin of their functional properties. The anisotropic orientation of the cationic dye inside the ZL channel is unambiguously determined and understood. The most stable orientation of MeAcr+, which features both its long and short molecular axes nearly perpendicular to the channel axis, is mainly determined by dye-ZL electrostatic interactions but also depends on the cosolvent water. In ZL, MeAcr+ is not hydrogen bonded to water or ZL framework oxygens and is hydrophobically solvated by water molecules. These findings further support the hypothesis that the cosolvent can importantly influence properties of dye-zeolite composites. Of relevance for a deeper comprehension of the physical chemistry of these hybrids is the observation that trivial energy transfer processes (self-absorption) are often playing a significant role in the optical properties of the composites.de_CH
dc.language.isoende_CH
dc.publisherAmerican Chemical Societyde_CH
dc.relation.ispartofLangmuirde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectOrientationde_CH
dc.subjectDyede_CH
dc.subjectComputationalde_CH
dc.subjectZeolitede_CH
dc.subject.ddc540: Chemiede_CH
dc.titleHost-guest interactions and orientation of dyes in the one-dimensional channels of zeolite Lde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
zhaw.organisationalunitInstitut für Chemie und Biotechnologie (ICBT)de_CH
dc.identifier.doi10.1021/la400579wde_CH
zhaw.funding.euNode_CH
zhaw.issue29de_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end9198de_CH
zhaw.pages.start9188de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume29de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
zhaw.webfeedPolymerchemiede_CH
Appears in collections:Publikationen Life Sciences und Facility Management

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Fois, E., Tabacchi, G., Devaux, A., Belser, P., Brühwiler, D., & Calzaferri, G. (2013). Host-guest interactions and orientation of dyes in the one-dimensional channels of zeolite L. Langmuir, 29(29), 9188–9198. https://doi.org/10.1021/la400579w
Fois, E. et al. (2013) ‘Host-guest interactions and orientation of dyes in the one-dimensional channels of zeolite L’, Langmuir, 29(29), pp. 9188–9198. Available at: https://doi.org/10.1021/la400579w.
E. Fois, G. Tabacchi, A. Devaux, P. Belser, D. Brühwiler, and G. Calzaferri, “Host-guest interactions and orientation of dyes in the one-dimensional channels of zeolite L,” Langmuir, vol. 29, no. 29, pp. 9188–9198, 2013, doi: 10.1021/la400579w.
FOIS, Ettore, Gloria TABACCHI, André DEVAUX, Peter BELSER, Dominik BRÜHWILER und Gion CALZAFERRI, 2013. Host-guest interactions and orientation of dyes in the one-dimensional channels of zeolite L. Langmuir. 2013. Bd. 29, Nr. 29, S. 9188–9198. DOI 10.1021/la400579w
Fois, Ettore, Gloria Tabacchi, André Devaux, Peter Belser, Dominik Brühwiler, and Gion Calzaferri. 2013. “Host-Guest Interactions and Orientation of Dyes in the One-Dimensional Channels of Zeolite L.” Langmuir 29 (29): 9188–98. https://doi.org/10.1021/la400579w.
Fois, Ettore, et al. “Host-Guest Interactions and Orientation of Dyes in the One-Dimensional Channels of Zeolite L.” Langmuir, vol. 29, no. 29, 2013, pp. 9188–98, https://doi.org/10.1021/la400579w.


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