| Publication type: | Article in scientific journal |
| Type of review: | Peer review (publication) |
| Title: | On the significance of the anchoring group in the design of antenna materials based on phthalocyanine stopcocks and zeolite L |
| Authors: | López-Duarte, Ismael Dieu, Le-Quyenh Dolamic, Igor Martínez-Díaz, M. Victoria Torres, Tomás Calzaferri, Gion Brühwiler, Dominik |
| DOI: | 10.1002/chem.201002210 |
| Published in: | Chemistry - A European Journal |
| Volume(Issue): | 17 |
| Issue: | 6 |
| Page(s): | 1855 |
| Pages to: | 1862 |
| Issue Date: | 2011 |
| Publisher / Ed. Institution: | Wiley |
| ISSN: | 0947-6539 1521-3765 |
| Language: | English |
| Subjects: | ICBC; 2011; Zeolite; Phthalocyanine |
| Subject (DDC): | 540: Chemistry |
| Abstract: | The synthesis of stopcocks based on zinc phthalocyanine for selective adsorption at the channel entrances of zeolite L is reported. The introduction of either an inert SiMe3 moiety, an imidazolium cation or a reactive isothiocyanate (NCS) group allows attachment to the channel entrances of zeolite L through van der Waals interactions, electrostatic interactions, or covalent binding, respectively. Stopcocks that rely on van-der-Waals-driven adsorption require careful selection of the solvent used for the deposition onto the zeolite surface to avoid a nonspecific distribution of the molecules. Regarding the design of photonic antenna systems, a stopcock with a cationic tail was found to be the most convenient, based on the observation that efficient energy transfer from molecules located in the zeolite nanochannels is more readily obtained than in the other cases. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/2666 |
| Fulltext version: | Published version |
| License (according to publishing contract): | Licence according to publishing contract |
| Departement: | Life Sciences and Facility Management |
| Organisational Unit: | Institute of Chemistry and Biotechnology (ICBT) |
| Appears in collections: | Publikationen Life Sciences und Facility Management |
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López-Duarte, I., Dieu, L.-Q., Dolamic, I., Martínez-Díaz, M. V., Torres, T., Calzaferri, G., & Brühwiler, D. (2011). On the significance of the anchoring group in the design of antenna materials based on phthalocyanine stopcocks and zeolite L. Chemistry - A European Journal, 17(6), 1855–1862. https://doi.org/10.1002/chem.201002210
López-Duarte, I. et al. (2011) ‘On the significance of the anchoring group in the design of antenna materials based on phthalocyanine stopcocks and zeolite L’, Chemistry - A European Journal, 17(6), pp. 1855–1862. Available at: https://doi.org/10.1002/chem.201002210.
I. López-Duarte et al., “On the significance of the anchoring group in the design of antenna materials based on phthalocyanine stopcocks and zeolite L,” Chemistry - A European Journal, vol. 17, no. 6, pp. 1855–1862, 2011, doi: 10.1002/chem.201002210.
LÓPEZ-DUARTE, Ismael, Le-Quyenh DIEU, Igor DOLAMIC, M. Victoria MARTÍNEZ-DÍAZ, Tomás TORRES, Gion CALZAFERRI und Dominik BRÜHWILER, 2011. On the significance of the anchoring group in the design of antenna materials based on phthalocyanine stopcocks and zeolite L. Chemistry - A European Journal. 2011. Bd. 17, Nr. 6, S. 1855–1862. DOI 10.1002/chem.201002210
López-Duarte, Ismael, Le-Quyenh Dieu, Igor Dolamic, M. Victoria Martínez-Díaz, Tomás Torres, Gion Calzaferri, and Dominik Brühwiler. 2011. “On the Significance of the Anchoring Group in the Design of Antenna Materials Based on Phthalocyanine Stopcocks and Zeolite L.” Chemistry - A European Journal 17 (6): 1855–62. https://doi.org/10.1002/chem.201002210.
López-Duarte, Ismael, et al. “On the Significance of the Anchoring Group in the Design of Antenna Materials Based on Phthalocyanine Stopcocks and Zeolite L.” Chemistry - A European Journal, vol. 17, no. 6, 2011, pp. 1855–62, https://doi.org/10.1002/chem.201002210.
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