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dc.contributor.authorYeretzian, Chahan-
dc.contributor.authorHermann, Robert H.-
dc.contributor.authorUngar, Horst-
dc.contributor.authorSelzle, Heinrich L.-
dc.contributor.authorSchlag, Edward W.-
dc.contributor.authorLin, Sheng H.-
dc.date.accessioned2018-04-18T14:09:49Z-
dc.date.available2018-04-18T14:09:49Z-
dc.date.issued1995-06-09-
dc.identifier.issn0009-2614de_CH
dc.identifier.issn1873-4448de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/5339-
dc.description.abstractRecently we reported on vibrationally resolved spectra of the ionic ground state of Ag2+ via ZEKE spectroscopy. The vibronic intensity distributions could not be interpreted within the Franck-Condon scheme. Here, we show that it is possible to overcome this discrepancy by invoking the breakdown of the Born-Oppenheimer approximation in the ZEKE states of silver dimer. A comparison of the spectral structure of the direct ion signal with simultaneously recorded ZEKE band profiles further illustrates this non-Franck-Condon behavior.de_CH
dc.language.isoende_CH
dc.publisherElsevierde_CH
dc.relation.ispartofChemical Physics Lettersde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectZekede_CH
dc.subjectSilver clusterde_CH
dc.subjectBorn-oppenheimer approximationde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleBreakdown of the born-oppenheimer approximation in ZEKE states of Ag2de_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
zhaw.publisher.placeAmsterdamde_CH
dc.identifier.doi10.1016/0009-2614(95)00441-6de_CH
zhaw.funding.euNode_CH
zhaw.issue1-3de_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end66de_CH
zhaw.pages.start61de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume239de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
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Yeretzian, C., Hermann, R. H., Ungar, H., Selzle, H. L., Schlag, E. W., & Lin, S. H. (1995). Breakdown of the born-oppenheimer approximation in ZEKE states of Ag2. Chemical Physics Letters, 239(1-3), 61–66. https://doi.org/10.1016/0009-2614(95)00441-6
Yeretzian, C. et al. (1995) ‘Breakdown of the born-oppenheimer approximation in ZEKE states of Ag2’, Chemical Physics Letters, 239(1-3), pp. 61–66. Available at: https://doi.org/10.1016/0009-2614(95)00441-6.
C. Yeretzian, R. H. Hermann, H. Ungar, H. L. Selzle, E. W. Schlag, and S. H. Lin, “Breakdown of the born-oppenheimer approximation in ZEKE states of Ag2,” Chemical Physics Letters, vol. 239, no. 1-3, pp. 61–66, Jun. 1995, doi: 10.1016/0009-2614(95)00441-6.
YERETZIAN, Chahan, Robert H. HERMANN, Horst UNGAR, Heinrich L. SELZLE, Edward W. SCHLAG und Sheng H. LIN, 1995. Breakdown of the born-oppenheimer approximation in ZEKE states of Ag2. Chemical Physics Letters. 9 Juni 1995. Bd. 239, Nr. 1-3, S. 61–66. DOI 10.1016/0009-2614(95)00441-6
Yeretzian, Chahan, Robert H. Hermann, Horst Ungar, Heinrich L. Selzle, Edward W. Schlag, and Sheng H. Lin. 1995. “Breakdown of the Born-Oppenheimer Approximation in ZEKE States of Ag2.” Chemical Physics Letters 239 (1-3): 61–66. https://doi.org/10.1016/0009-2614(95)00441-6.
Yeretzian, Chahan, et al. “Breakdown of the Born-Oppenheimer Approximation in ZEKE States of Ag2.” Chemical Physics Letters, vol. 239, no. 1-3, June 1995, pp. 61–66, https://doi.org/10.1016/0009-2614(95)00441-6.


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