Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lindinger, Christian | - |
dc.contributor.author | Pollien, Philippe | - |
dc.contributor.author | Ali, Santo | - |
dc.contributor.author | Yeretzian, Chahan | - |
dc.contributor.author | Blank, Imre | - |
dc.contributor.author | Tilmann, Märk | - |
dc.date.accessioned | 2018-04-23T09:21:13Z | - |
dc.date.available | 2018-04-23T09:21:13Z | - |
dc.date.issued | 2005-05-26 | - |
dc.identifier.issn | 0003-2700 | de_CH |
dc.identifier.issn | 1520-6882 | de_CH |
dc.identifier.uri | https://digitalcollection.zhaw.ch/handle/11475/5468 | - |
dc.description.abstract | Interest in on-line measurements of volatile organic compounds (VOCs) is increasing, as sensitive, compact, and affordable direct inlet mass spectrometers are becoming available. Proton-transfer reaction mass spectrometry (PTR-MS) distinguishes itself by its high sensitivity (low ppt range), high time resolution (200 ms), little ionization-induced fragmentation, and ionization efficiency independent of the compound to be analyzed. Yet, PTR-MS has a shortcoming. It is a one-dimensional technique that characterizes compounds only via their mass, which is not sufficient for positive identification. Here, we introduce a technical and analytical extension of PTR-MS, which removes this shortcoming, while preserving its salient and unique features. Combining separation of VOCs by gas chromatography (GC) with simultaneous and parallel detection of the GC effluent by PTR-MS and electron impact MS, an unambiguous interpretation of complex PTR-MS spectra becomes feasible. This novel development is discussed on the basis of characteristic performance parameters, such as resolution, linear range, and detection limit. The recently developed drift tube with a reduced reaction volume is crucial to exploit the full potential of the setup. We illustrate the performance of the novel setup by analyzing a complex food system. | de_CH |
dc.language.iso | en | de_CH |
dc.publisher | American Chemical Society | de_CH |
dc.relation.ispartof | Analytical Chemistry | de_CH |
dc.rights | Licence according to publishing contract | de_CH |
dc.subject | PTR-MS | de_CH |
dc.subject.ddc | 540: Chemie | de_CH |
dc.title | Unambiguous identification of volatile organic compounds by proton-transfer-reaction mass-spectrometry (PTR-MS) coupled with GC-MS | de_CH |
dc.type | Beitrag in wissenschaftlicher Zeitschrift | de_CH |
dcterms.type | Text | de_CH |
zhaw.departement | Life Sciences und Facility Management | de_CH |
zhaw.organisationalunit | Institut für Chemie und Biotechnologie (ICBT) | de_CH |
zhaw.publisher.place | Columbus | de_CH |
dc.identifier.doi | 10.1021/ac0501240 | de_CH |
zhaw.funding.eu | No | de_CH |
zhaw.issue | 13 | de_CH |
zhaw.originated.zhaw | Yes | de_CH |
zhaw.pages.end | 4124 | de_CH |
zhaw.pages.start | 4117 | de_CH |
zhaw.publication.status | publishedVersion | de_CH |
zhaw.volume | 77 | de_CH |
zhaw.publication.review | Peer review (Publikation) | de_CH |
Appears in collections: | Publikationen Life Sciences und Facility Management |
Files in This Item:
There are no files associated with this item.
Show simple item record
Lindinger, C., Pollien, P., Ali, S., Yeretzian, C., Blank, I., & Tilmann, M. (2005). Unambiguous identification of volatile organic compounds by proton-transfer-reaction mass-spectrometry (PTR-MS) coupled with GC-MS. Analytical Chemistry, 77(13), 4117–4124. https://doi.org/10.1021/ac0501240
Lindinger, C. et al. (2005) ‘Unambiguous identification of volatile organic compounds by proton-transfer-reaction mass-spectrometry (PTR-MS) coupled with GC-MS’, Analytical Chemistry, 77(13), pp. 4117–4124. Available at: https://doi.org/10.1021/ac0501240.
C. Lindinger, P. Pollien, S. Ali, C. Yeretzian, I. Blank, and M. Tilmann, “Unambiguous identification of volatile organic compounds by proton-transfer-reaction mass-spectrometry (PTR-MS) coupled with GC-MS,” Analytical Chemistry, vol. 77, no. 13, pp. 4117–4124, May 2005, doi: 10.1021/ac0501240.
LINDINGER, Christian, Philippe POLLIEN, Santo ALI, Chahan YERETZIAN, Imre BLANK und Märk TILMANN, 2005. Unambiguous identification of volatile organic compounds by proton-transfer-reaction mass-spectrometry (PTR-MS) coupled with GC-MS. Analytical Chemistry. 26 Mai 2005. Bd. 77, Nr. 13, S. 4117–4124. DOI 10.1021/ac0501240
Lindinger, Christian, Philippe Pollien, Santo Ali, Chahan Yeretzian, Imre Blank, and Märk Tilmann. 2005. “Unambiguous Identification of Volatile Organic Compounds by Proton-Transfer-Reaction Mass-Spectrometry (PTR-MS) Coupled with GC-MS.” Analytical Chemistry 77 (13): 4117–24. https://doi.org/10.1021/ac0501240.
Lindinger, Christian, et al. “Unambiguous Identification of Volatile Organic Compounds by Proton-Transfer-Reaction Mass-Spectrometry (PTR-MS) Coupled with GC-MS.” Analytical Chemistry, vol. 77, no. 13, May 2005, pp. 4117–24, https://doi.org/10.1021/ac0501240.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.