| Publication type: | Article in scientific journal |
| Type of review: | Peer review (publication) |
| Title: | Two-phase dynamic modeling of the PEMFCs and simulation of cyclo-voltammograms |
| Authors: | Ziegler, Christoph Yu, Hong Mei Schumacher, Jürgen |
| DOI: | 10.1149/1.1946408 |
| Published in: | Journal of the Electrochemical Society |
| Volume(Issue): | 152 |
| Issue: | 8 |
| Page(s): | 1555 |
| Pages to: | 1567 |
| Issue Date: | 2005 |
| Publisher / Ed. Institution: | Electrochemical Society |
| ISSN: | 0013-4651 1945-7111 |
| Language: | English |
| Subjects: | Fuel cells; Dynamic modelling; Pemfc; Simulation |
| Subject (DDC): | 621.3: Electrical, communications, control engineering |
| Abstract: | A mathematical model is developed that is based on a coupled system of partial differential equations. The model contains a dynamic and two-phase description of the proton exchange membrane fuel cell (PEMFC) and a membrane model that accounts for Schroeder’s paradox. The mass transport in the gas phase and in the liquid phase is considered as well as the phase transition between liquid water and water vapor. The transport of charges and the electrochemical reactions are part of the model. A potential sweep experiment is simulated using the mathematical model and measured using a test cell with an active area of 1cm2. In this way, the dynamic effect of liquid water formation and transport on the current-voltage characteristic of the fuel cell is investigated. A hysteresis effect is found in the measured time-dependent current-voltage relation. The limiting current density is time-dependent. Qualitative agreement of simulated and measured results is achieved. An analysis of the observed hysteresis of the current-voltage characteristics, based on the modeling results, is given. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/11579 |
| Fulltext version: | Published version |
| License (according to publishing contract): | Licence according to publishing contract |
| Departement: | School of Engineering |
| Organisational Unit: | Institute of Computational Physics (ICP) |
| Appears in collections: | Publikationen School of Engineering |
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Ziegler, C., Yu, H. M., & Schumacher, J. (2005). Two-phase dynamic modeling of the PEMFCs and simulation of cyclo-voltammograms. Journal of the Electrochemical Society, 152(8), 1555–1567. https://doi.org/10.1149/1.1946408
Ziegler, C., Yu, H.M. and Schumacher, J. (2005) ‘Two-phase dynamic modeling of the PEMFCs and simulation of cyclo-voltammograms’, Journal of the Electrochemical Society, 152(8), pp. 1555–1567. Available at: https://doi.org/10.1149/1.1946408.
C. Ziegler, H. M. Yu, and J. Schumacher, “Two-phase dynamic modeling of the PEMFCs and simulation of cyclo-voltammograms,” Journal of the Electrochemical Society, vol. 152, no. 8, pp. 1555–1567, 2005, doi: 10.1149/1.1946408.
ZIEGLER, Christoph, Hong Mei YU und Jürgen SCHUMACHER, 2005. Two-phase dynamic modeling of the PEMFCs and simulation of cyclo-voltammograms. Journal of the Electrochemical Society. 2005. Bd. 152, Nr. 8, S. 1555–1567. DOI 10.1149/1.1946408
Ziegler, Christoph, Hong Mei Yu, and Jürgen Schumacher. 2005. “Two-Phase Dynamic Modeling of the PEMFCs and Simulation of Cyclo-Voltammograms.” Journal of the Electrochemical Society 152 (8): 1555–67. https://doi.org/10.1149/1.1946408.
Ziegler, Christoph, et al. “Two-Phase Dynamic Modeling of the PEMFCs and Simulation of Cyclo-Voltammograms.” Journal of the Electrochemical Society, vol. 152, no. 8, 2005, pp. 1555–67, https://doi.org/10.1149/1.1946408.
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