Model studies of diffusion in glassy and polymer ion conductors

Dürr, Oliver; Pendzig, Peter; Dieterich, Wolfgang; Nitzan, Abraham

Publication type:	Conference paper
Type of review:	Peer review (publication)
Title:	Model studies of diffusion in glassy and polymer ion conductors
Authors:	Dürr, Oliver Pendzig, Peter Dieterich, Wolfgang Nitzan, Abraham
Proceedings:	Solid State Ionics: Science & Technology Proceedings of the 6th Asian Conference on Solid State Ionics
Editors of the parent work:	Chowdari, B. V. R. Chandra, S.
Page(s):	33
Conference details:	6th Asian Conference on Solid State Ionics, Singapore, 1998
Issue Date:	1998
Publisher / Ed. Institution:	World Scientific
Publisher / Ed. Institution:	Singapore
Language:	English
Subject (DDC):	530: Physics
Abstract:	Ion-conducting glasses and polymer systems show several characteristic peculiarities in their composition-dependent diffusion properties and in their dynamic response. First we give a brief review of the current understanding of the ion dynamics in network glasses in terms of stochastic theories. Secondly, a model for PEO(polyethylene-oxide)-based polymer electrolytes is described. The equation of state is calculated from the quasichemical approximation. Using this information together with Monte Carlo simulations of diffusion at constant volume, we obtain constant-pressure results for polymer chain and ion diffusion as a function of ion concentration. This theory allows us to make comparison with experiments which are carried out at constant pressure.
URI:	https://arxiv.org/pdf/cond-mat/0106196v1.pdf https://digitalcollection.zhaw.ch/handle/11475/13861
Fulltext version:	Published version
License (according to publishing contract):	Licence according to publishing contract
Departement:	School of Engineering
Organisational Unit:	Institute of Data Analysis and Process Design (IDP)
Appears in collections:	Publikationen School of Engineering

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