Please use this identifier to cite or link to this item:
https://doi.org/10.21256/zhaw-3227
Publication type: | Article in scientific journal |
Type of review: | Peer review (publication) |
Title: | Sulphur tolerant diesel oxidation catalysts by noble metal alloying |
Authors: | Franken, Tanja Vieweger, Elisabeth Klimera, Andreas Hug, Michael Heel, Andre |
DOI: | 10.21256/zhaw-3227 10.1016/j.catcom.2019.105732 |
Published in: | Catalysis Communications |
Volume(Issue): | 219 |
Issue: | 105732 |
Issue Date: | 2019 |
Publisher / Ed. Institution: | Elsevier |
ISSN: | 1566-7367 |
Language: | English |
Subjects: | Sulphur tolerance; NO oxidation; Mn-Pt alloy; deNOx; Manganese; Platinum |
Subject (DDC): | 620: Engineering |
Abstract: | A series of Mn-alloyed Pt supported catalysts were investigated for the NO oxidation reaction applied in diesel oxidation catalysts under sulphur-containing conditions. The observed NO oxidation conversion correlated to the Pt amount in the catalyst under sulphur-free conditions. In the presence of SO2 in the feed, the Pt/Al2O3 catalyst heavily deactivated resulting in the lowest performance compared to Mn-alloyed Pt catalysts. Already small amounts of Mn improved the SO2-resistance significantly. Whilst pure Pt/Al2O3 catalyst deactivates fully within the first 30 min under NO oxidation conditions including 300 ppm SO2, an alloy with a Mn to Pt ratio of 1:1 performed with a remarkable high catalytic stability for the NO oxidation over at least 70 h under continuous testing conditions. |
URI: | https://digitalcollection.zhaw.ch/handle/11475/17358 |
Fulltext version: | Accepted version |
License (according to publishing contract): | CC BY-NC-ND 4.0: Attribution - Non commercial - No derivatives 4.0 International |
Restricted until: | 2021-07-01 |
Departement: | School of Engineering |
Organisational Unit: | Institute of Materials and Process Engineering (IMPE) |
Published as part of the ZHAW project: | NANODOC: Entwicklung eines neuartigen, nanostrukturierten Diesel-Oxidationskatalysators (DOC) |
Appears in collections: | Publikationen School of Engineering |
Files in This Item:
File | Description | Size | Format | |
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1-s2.0-S1566736719301943-main.pdf | Accepted Version | 2.58 MB | Adobe PDF | View/Open |
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Franken, T., Vieweger, E., Klimera, A., Hug, M., & Heel, A. (2019). Sulphur tolerant diesel oxidation catalysts by noble metal alloying. Catalysis Communications, 219(105732). https://doi.org/10.21256/zhaw-3227
Franken, T. et al. (2019) ‘Sulphur tolerant diesel oxidation catalysts by noble metal alloying’, Catalysis Communications, 219(105732). Available at: https://doi.org/10.21256/zhaw-3227.
T. Franken, E. Vieweger, A. Klimera, M. Hug, and A. Heel, “Sulphur tolerant diesel oxidation catalysts by noble metal alloying,” Catalysis Communications, vol. 219, no. 105732, 2019, doi: 10.21256/zhaw-3227.
FRANKEN, Tanja, Elisabeth VIEWEGER, Andreas KLIMERA, Michael HUG und Andre HEEL, 2019. Sulphur tolerant diesel oxidation catalysts by noble metal alloying. Catalysis Communications. 2019. Bd. 219, Nr. 105732. DOI 10.21256/zhaw-3227
Franken, Tanja, Elisabeth Vieweger, Andreas Klimera, Michael Hug, and Andre Heel. 2019. “Sulphur Tolerant Diesel Oxidation Catalysts by Noble Metal Alloying.” Catalysis Communications 219 (105732). https://doi.org/10.21256/zhaw-3227.
Franken, Tanja, et al. “Sulphur Tolerant Diesel Oxidation Catalysts by Noble Metal Alloying.” Catalysis Communications, vol. 219, no. 105732, 2019, https://doi.org/10.21256/zhaw-3227.
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