Please use this identifier to cite or link to this item:
https://doi.org/10.21256/zhaw-22734
Publication type: | Article in scientific journal |
Type of review: | Peer review (publication) |
Title: | The bottlenecks of Cs2AgBiBr6 solar cells : how contacts and slow transients limit the performance |
Authors: | Sirtl, Maximilian T. Ebadi, Firouzeh van Gorkom, Bas T. Ganswindt, Patrick Janssen, René A. J. Bein, Thomas Tress, Wolfgang |
et. al: | No |
DOI: | 10.1002/adom.202100202 10.21256/zhaw-22734 |
Published in: | Advanced Optical Materials |
Volume(Issue): | 9 |
Issue: | 14 |
Page(s): | 2100202 |
Issue Date: | 21-Jun-2021 |
Publisher / Ed. Institution: | Wiley |
ISSN: | 2195-1071 |
Language: | English |
Subject (DDC): | 621.3: Electrical, communications, control engineering |
Abstract: | Cs2AgBiBr6 has attracted much interest as a potential lead-free alternative for perovskite solar cells. Although this material offers encouraging optoelectronic features, severe bottlenecks limit the performance of the resulting solar cells to a power conversion efficiency of below 3%. Here, the performance-limiting factors of this material are investigated in full solar cells featuring various architectures. It is found that the photovoltaic parameters of Cs2AgBiBr6-based solar cells strongly depend on the scan speed of the J/V measurements, suggesting a strong impact of ionic conductivity in the material. Moreover, a sign change of the photocurrent for bias voltages above 0.9 V during the measurement of the external quantum efficiency (EQE) is revealed, which can be explained by non-selective contacts. The radiative loss of the VOC from sensitive subgap-EQE measurements is calculated and it is revealed that the loss is caused by a low external luminescence yield and therefore a high non-radiative recombination, supported by the first report of a strongly red shifted electroluminescence signal between 800 and 1000 nm. Altogether, these results point to a poor selectivity of the contacts and charge transport layers, caused by poor energy level alignment that can be overcome by optimizing the architecture of the solar cell. |
URI: | https://digitalcollection.zhaw.ch/handle/11475/22734 |
Fulltext version: | Published version |
License (according to publishing contract): | CC BY-NC 4.0: Attribution - Non commercial 4.0 International |
Departement: | School of Engineering |
Organisational Unit: | Institute of Computational Physics (ICP) |
Published as part of the ZHAW project: | Modellierung und Charakterisierung von neuartigen optoelektronischen Bauelementen |
Appears in collections: | Publikationen School of Engineering |
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File | Description | Size | Format | |
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2021_Sirtl-etal_The-bottlenecks-of-Cs2AgBiBr6-solar-cells.pdf | 3.21 MB | Adobe PDF | View/Open |
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Sirtl, M. T., Ebadi, F., van Gorkom, B. T., Ganswindt, P., Janssen, R. A. J., Bein, T., & Tress, W. (2021). The bottlenecks of Cs2AgBiBr6 solar cells : how contacts and slow transients limit the performance. Advanced Optical Materials, 9(14), 2100202. https://doi.org/10.1002/adom.202100202
Sirtl, M.T. et al. (2021) ‘The bottlenecks of Cs2AgBiBr6 solar cells : how contacts and slow transients limit the performance’, Advanced Optical Materials, 9(14), p. 2100202. Available at: https://doi.org/10.1002/adom.202100202.
M. T. Sirtl et al., “The bottlenecks of Cs2AgBiBr6 solar cells : how contacts and slow transients limit the performance,” Advanced Optical Materials, vol. 9, no. 14, p. 2100202, Jun. 2021, doi: 10.1002/adom.202100202.
SIRTL, Maximilian T., Firouzeh EBADI, Bas T. VAN GORKOM, Patrick GANSWINDT, René A. J. JANSSEN, Thomas BEIN und Wolfgang TRESS, 2021. The bottlenecks of Cs2AgBiBr6 solar cells : how contacts and slow transients limit the performance. Advanced Optical Materials. 21 Juni 2021. Bd. 9, Nr. 14, S. 2100202. DOI 10.1002/adom.202100202
Sirtl, Maximilian T., Firouzeh Ebadi, Bas T. van Gorkom, Patrick Ganswindt, René A. J. Janssen, Thomas Bein, and Wolfgang Tress. 2021. “The Bottlenecks of Cs2AgBiBr6 Solar Cells : How Contacts and Slow Transients Limit the Performance.” Advanced Optical Materials 9 (14): 2100202. https://doi.org/10.1002/adom.202100202.
Sirtl, Maximilian T., et al. “The Bottlenecks of Cs2AgBiBr6 Solar Cells : How Contacts and Slow Transients Limit the Performance.” Advanced Optical Materials, vol. 9, no. 14, June 2021, p. 2100202, https://doi.org/10.1002/adom.202100202.
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