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Please use this identifier to cite or link to this item: https://doi.org/10.21256/zhaw-30320
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dc.contributor.authorShin, Bong-Rim-
dc.contributor.authorPuc, Uros-
dc.contributor.authorPark, Yu-Jin-
dc.contributor.authorKim, Dong-Joo-
dc.contributor.authorLee, Chae-Won-
dc.contributor.authorYoon, Woojin-
dc.contributor.authorYun, Hoseop-
dc.contributor.authorKim, Chaeyoon-
dc.contributor.authorRotermund, Fabian-
dc.contributor.authorJazbinsek, Mojca-
dc.contributor.authorKwon, O-Pil-
dc.date.accessioned2024-03-22T09:43:26Z-
dc.date.available2024-03-22T09:43:26Z-
dc.date.issued2023-12-06-
dc.identifier.issn2198-3844de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/30320-
dc.description.abstractIn the development of new organic crystals for nonlinear optical and terahertz (THz) applications, it is very challenging to achieve the essentially required non-centrosymmetric molecular arrangement. Moreover, the resulting crystal structure is mostly unpredictable due to highly dipolar molecular components with complex functional substituents. In this work, new organic salt crystals with top-level macroscopic optical nonlinearity by controlling the van der Waals volume (VvdW ), rather than by trial and error, are logically designed. When the VvdW of molecular ionic components varies, the corresponding crystal symmetry shows an observable trend: change from centrosymmetric to non-centrosymmetric and back to centrosymmetric. All non-centrosymmetric crystals exhibit an isomorphic P1 crystal structure with an excellent macroscopic second-order nonlinear optical response. Apart from the top-level macroscopic optical nonlinearity, new organic crystals introducing highly electronegative fluorinated substituents with strong secondary bonding ability show excellent performance in efficient and broadband THz wave generation, high crystal density, high thermal stability, and good bulk crystal growth ability.de_CH
dc.language.isoende_CH
dc.publisherWileyde_CH
dc.relation.ispartofAdvanced Sciencede_CH
dc.rightshttp://creativecommons.org/licenses/by/4.0/de_CH
dc.subjectCrystal structure controlde_CH
dc.subjectNonlinear opticsde_CH
dc.subjectOrganic crystalsde_CH
dc.subjectTerahertz photonicsde_CH
dc.subjectVan der Waals volumede_CH
dc.subject.ddc540: Chemiede_CH
dc.titleDesign of high-performance organic nonlinear optical and terahertz crystals by controlling the van der Waals volumede_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementSchool of Engineeringde_CH
zhaw.organisationalunitInstitute of Computational Physics (ICP)de_CH
dc.identifier.doi10.1002/advs.202304767de_CH
dc.identifier.doi10.21256/zhaw-30320-
dc.identifier.pmid37867211de_CH
zhaw.funding.euNode_CH
zhaw.issue34de_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.start2304767de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume10de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
zhaw.funding.snf188194de_CH
zhaw.webfeedPhotonicsde_CH
zhaw.author.additionalNode_CH
zhaw.display.portraitYesde_CH
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Shin, B.-R., Puc, U., Park, Y.-J., Kim, D.-J., Lee, C.-W., Yoon, W., Yun, H., Kim, C., Rotermund, F., Jazbinsek, M., & Kwon, O.-P. (2023). Design of high-performance organic nonlinear optical and terahertz crystals by controlling the van der Waals volume. Advanced Science, 10(34), 2304767. https://doi.org/10.1002/advs.202304767
Shin, B.-R. et al. (2023) ‘Design of high-performance organic nonlinear optical and terahertz crystals by controlling the van der Waals volume’, Advanced Science, 10(34), p. 2304767. Available at: https://doi.org/10.1002/advs.202304767.
B.-R. Shin et al., “Design of high-performance organic nonlinear optical and terahertz crystals by controlling the van der Waals volume,” Advanced Science, vol. 10, no. 34, p. 2304767, Dec. 2023, doi: 10.1002/advs.202304767.
SHIN, Bong-Rim, Uros PUC, Yu-Jin PARK, Dong-Joo KIM, Chae-Won LEE, Woojin YOON, Hoseop YUN, Chaeyoon KIM, Fabian ROTERMUND, Mojca JAZBINSEK und O-Pil KWON, 2023. Design of high-performance organic nonlinear optical and terahertz crystals by controlling the van der Waals volume. Advanced Science. 6 Dezember 2023. Bd. 10, Nr. 34, S. 2304767. DOI 10.1002/advs.202304767
Shin, Bong-Rim, Uros Puc, Yu-Jin Park, Dong-Joo Kim, Chae-Won Lee, Woojin Yoon, Hoseop Yun, et al. 2023. “Design of High-Performance Organic Nonlinear Optical and Terahertz Crystals by Controlling the van Der Waals Volume.” Advanced Science 10 (34): 2304767. https://doi.org/10.1002/advs.202304767.
Shin, Bong-Rim, et al. “Design of High-Performance Organic Nonlinear Optical and Terahertz Crystals by Controlling the van Der Waals Volume.” Advanced Science, vol. 10, no. 34, Dec. 2023, p. 2304767, https://doi.org/10.1002/advs.202304767.


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