Please use this identifier to cite or link to this item: https://doi.org/10.21256/zhaw-4135
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dc.contributor.authorSiegmann, Konstantin-
dc.contributor.authorSterchi, Robert-
dc.contributor.authorWidler, Roland-
dc.contributor.authorHirayama, Martina-
dc.date.accessioned2018-02-26T09:19:09Z-
dc.date.available2018-02-26T09:19:09Z-
dc.date.issued2013-02-01-
dc.identifier.issn1097-4628de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/3047-
dc.description.abstractThe precipitation of calcium carbonate from hard water, commonly known as calcification or scaling, is a widespread nuisance. To avoid scaling, a physical or chemical pretreatment of water is often employed, such as ion exchange, addition of complexing agents, or the use of magnetic and electric fields. Our approach is to construct surfaces to which calcium carbonate crystals do not adhere. Here, we show that by the use of particular copolymer additives, polyethylene can be made lime repellent. The copolymers have the formula: polyethylene-block-poly(ethylene glycol) and are compounded into the polyethylene. Twelve such additives were investigated and three displayed anticalcification activity. The effective copolymers were investigated by mass spectrometry. Infrared spectroscopy of copolymer/polyethylene blends revealed that the concentration of the additive in the matrix correlates to a specific absorption band. Stability tests against hot water showed that the anticalcification activity was maintained over the timeframe investigated.de_CH
dc.language.isoende_CH
dc.publisherWileyde_CH
dc.relation.ispartofJournal of Applied Polymer Sciencede_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectSurfaces and interfacesde_CH
dc.subjectCrystallizationde_CH
dc.subjectAdsorptionde_CH
dc.subjectPhase behaviorde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleLime repellent polyethylene additivesde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementSchool of Engineeringde_CH
zhaw.organisationalunitInstitute of Materials and Process Engineering (IMPE)de_CH
zhaw.publisher.placeNew Yorkde_CH
dc.identifier.doi10.21256/zhaw-4135-
dc.identifier.doi10.1002/APP.38928de_CH
zhaw.funding.euNode_CH
zhaw.issue5de_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end2734de_CH
zhaw.pages.start2727de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume129de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
zhaw.webfeedPolymere Beschichtungende_CH
Appears in collections:Publikationen School of Engineering

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Siegmann, K., Sterchi, R., Widler, R., & Hirayama, M. (2013). Lime repellent polyethylene additives. Journal of Applied Polymer Science, 129(5), 2727–2734. https://doi.org/10.21256/zhaw-4135
Siegmann, K. et al. (2013) ‘Lime repellent polyethylene additives’, Journal of Applied Polymer Science, 129(5), pp. 2727–2734. Available at: https://doi.org/10.21256/zhaw-4135.
K. Siegmann, R. Sterchi, R. Widler, and M. Hirayama, “Lime repellent polyethylene additives,” Journal of Applied Polymer Science, vol. 129, no. 5, pp. 2727–2734, Feb. 2013, doi: 10.21256/zhaw-4135.
SIEGMANN, Konstantin, Robert STERCHI, Roland WIDLER und Martina HIRAYAMA, 2013. Lime repellent polyethylene additives. Journal of Applied Polymer Science. 1 Februar 2013. Bd. 129, Nr. 5, S. 2727–2734. DOI 10.21256/zhaw-4135
Siegmann, Konstantin, Robert Sterchi, Roland Widler, and Martina Hirayama. 2013. “Lime Repellent Polyethylene Additives.” Journal of Applied Polymer Science 129 (5): 2727–34. https://doi.org/10.21256/zhaw-4135.
Siegmann, Konstantin, et al. “Lime Repellent Polyethylene Additives.” Journal of Applied Polymer Science, vol. 129, no. 5, Feb. 2013, pp. 2727–34, https://doi.org/10.21256/zhaw-4135.


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